From recollection (quite possibly inaccurate!) the ANZAC’s have a magazine capacity of +/- 500x or so 127mm rounds, depending on variants carried.
I’d be surprised if the AWD’s or Hunters had fewer than that planned if the ANZAC’s could carry so much.
I don’t think RAN / ADF is planning on any other calibre main gun any time soon. For starters it has specified Mk.45 Mod 4 for the Hobarts, Hunters and Mogamis, so that is a pretty big hint…
But it is also seeking a range of ammunition enhancements for these guns, starting with 127mm counter-UAS munitions:
Informed by recent conflicts in the Red and Black Seas the Royal Australian Navy is seeking new capabilities for its inventory of Mk45 5-inch guns | Ben Felton
www.australiandefence.com.au
And it is seeking local manufacturing, IP rights and development of additional ammunition natures…
French group Thales Australia and global defence and security firm EXPAL Systems S.A. (EXPAL) have joined forces to establish an Australian sovereign manufacturing capability for large calibre naval munitions and fuses. The agreement will facilitate the technology transfer to Australia of...
www.aumanufacturing.com.au
Given those decisions and related investment, it seems a pretty non-controversial matter to state the RAN has no apparent interest in changing the main gun systems it uses any time soon…